amphoteros

A post-scriptum on fluorine…

Hi all, I am glad that one of the readers reminded me about a classic work by Jack Dunitz. In addition to my personal response, I decided to post a link so that everyone can see it and save in their folders of “important papers”. 

http://onlinelibrary.wiley.com/doi/10.1002/chem.19970030115/abstract

The title says it all: a contradiction to what the Linclau study suggests. However, the Dunitz paper is primarily a crystallographic study, which is an important distinction. One comment: people no longer come up with really great titles. There is a monumental inscription in the title of the Dunitz contribution: “Organic Fluorine Hardly Ever Accepts Hydrogen Bonds”!